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I am unable to see the instances - make sure you are checking the correct AWS Region
I still dont see them as users in the org - make sure you are checking the correct AWS account
using SSO for users to get access to your AWS accounts is the best practice. You can manage users/groups and permissions for all accounts from a single place https://docs.aws.amazon.com/singlesignon/latest/userguide/useraccess.html
The default EC@ console only shows resources in the current region. On the AWS console I would recommend navisate to the "EC2" page" and click on "EC2 Global View" . Its typically on the elft corner 2nd from the top. For my USA based account the direct link is https://us-east-1.console.aws.amazon.com/ec2globalview/home
This will give youa. global view of all the VPCs and EC2s

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