HIVE_BAD_DATA: Error parsing field value '2021-10-31 22:00:00.0' for field 3: For input string: "2021-10-31 22:00:00.0"

I am reading files from S3 and using a Glue ETL job to populate a Data Catalog Table.

My S3 files look like this:

VID,ALTID,VTYPE,TIME,TIMEGMT,VALUE
ABC, ABC, DATAFEED,31-10-2021 22:00:00,01-11-2021 02:00:00,   11775.685

The scheme read in looks like this

root
|-- VID: string
|-- ALTID: string
|-- VTYPE: string
|-- TIME: string
|-- TIMEGMT: string
|-- VALUE: string

I am changing fields 3 and 4 from "strings" to timestamps, which matches the schema of my Data Catalog Table. I am also doing a few other transformations.

I am transforming them like so:

df = df.withColumn("time", to_timestamp("time", 'dd-MM-yyyy HH:mm:ss'))
df = df.withColumn("timegmt", to_timestamp("timegmt", 'dd-MM-yyyy HH:mm:ss'))

When I try to read the data with Athena, I get an error:

HIVE_BAD_DATA: Error parsing field value '2021-10-31 22:00:00.0' for field 3: For input string: "2021-10-31 22:00:00.0"

The Data Catalog Table Schema looks like this:

And the line in the run-1647806179090-part-r-00000 file it is choking on looks like this:

vid,altid,vtype,time,timegmt,value,filename
ABC,ABC, DATAFEED,"2021-10-31 22:00:00.0","2021-11-01 02:00:00.0",11775,"lf_buf_20211101_005904.csv"

Does anyone know why it would throw this error? I believe according to the documentation, this is the correct timestamp format.